In Situ Synthesis of Tetradentate Dye for Construction of Three-Dimensional Homochiral Phosphor
Source abstract
Abstract
Three-dimensional assembly of enantiopure D-camphoric acid and in situ synthesized tetradentate 1,2,4,5-tetra(4-pyridyl)benzene (TPB) ligand with tetrahedral Zn(2+) leads to a new homochiral four-connected luminescent material from which the novel TPB ligand can be isolated in the hydrated crystalline form.
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Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Luminescence and Fluorescent Materials · Molecular Sensors and Ion Detection
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry and Biochemistry, California State University, Long Beach, 1250 Bellflower Boulevard, Long Beach, California 90840, and Department of Chemistry, University of California, Riverside, California 92521
References (27)
Show source-provided references
1. Guillou N. · Angew. Chem., Int. Ed. · 2003 · 42 · 531410.1002/anie.200352520 ↗
2. Dybtsev D. N. · Inorg. Chem. · 2007 · 46 · 684310.1021/ic7009226 ↗
3. Yaghi O. M. · Nature · 2003 · 423 · 70510.1038/nature01650 ↗
4. Knope K. E. · Inorg. Chem. · 2007 · 46 · 660710.1021/ic700700e ↗
5. de Lill D. T. · Cryst. Growth Des. · 2007 · 7 · 239010.1021/cg700741v ↗
6. Ziegelgruber K. L. · J. Solid State Chem. · 2008 · 181 · 37310.1016/j.jssc.2007.12.008 ↗
7. Lai Y. L. · J. Am. Chem. Soc. · 2007 · 129 · 535010.1021/ja070733k ↗
8. Tsao C.-P. · Inorg. Chem. · 2006 · 45 · 636110.1021/ic0603959 ↗
9. Sheu C. Y. · Inorg. Chem. · 2006 · 45 · 189110.1021/ic0518475 ↗
10. Ma S. · J. Am. Chem. Soc. · 2007 · 129 · 185810.1021/ja067435s ↗
11. Ma S. · J. Am. Chem. Soc. · 2006 · 128 · 1173410.1021/ja063538z ↗
12. Rao V. K. · Inorg. Chem. · 2007 · 46 · 1078110.1021/ic7014594 ↗
13. Liu G. Z. · Angew. Chem., Int. Ed. · 2007 · 46 · 282710.1002/anie.200604921 ↗
14. Kesanli B. · Coord. Chem. Rev. · 2003 · 246 · 30510.1016/j.cct.2003.08.004 ↗
15. Wu C-D. · Chem. Commun. · 2006 · 3673
16. Zhang J. · Angew. Chem., Int. Ed. · 2007 · 46 · 611510.1002/anie.200701374 ↗
17. Zhang J. · J. Am. Chem. Soc. · 2007 · 129 · 1416810.1021/ja076532y ↗
18. Zhang J. · Angew. Chem., Int. Ed. · 2007 · 46 · 838810.1002/anie.200703008 ↗
19. Zhang J. · Chem. Mater. · 2007 · 19 · 508310.1021/cm071689a ↗
20. Zhang J. · Chem. Commun. · 2008 · 44410.1039/B715945E ↗
21. Lin Z. · J. Am. Chem. Soc. · 2007 · 129 · 488010.1021/ja070671y ↗
22. Zheng N. · Cryst. Growth Des. · 2007 · 7 · 257610.1021/cg0705456 ↗
23. Synthesis of1and2: Hydrothermal reaction ofd-H2cam (0.1100 g), TMDPy (0.1118 g), Zn(NO3)2·6H2O (0.3487 g), GeO2(0.0518 g), and Na2CO3(0.0595 g) in H2O (4 mL) solution (pH 5.36) was performed at 160 °C for 6 days, and the mixture was then cooled to room-temperature. Colorless crystals of1were obtained (0.092 g, 35% yield). The phase purity was supported by powder X-ray diffraction (see the Supporting Information, Figure S1). To isolate the in situ formed tetradentate liagnd, we placed the powder of1(0.052 g) in 0.02 mol/L HCl (3 mL) solution in a vial. The vial was heated at 100 °C for 24 h and then cooled to room temperature. Colorless needlelike crystals of TPB·2H2O(2)were obtained in 92% yield.
24. Zheng N. F. · J. Am. Chem. Soc. · 2002 · 124 · 968810.1021/ja020480p ↗
25. Crystal data for1: C46H50N4O10Zn2,Mr= 958.65, monoclinic, space groupP21,a= 12.8678(7) Å,b= 11.6950(5) Å,c= 15.7404(8) Å, β = 97.791(4)°,V= 2346.9(2) Å3,Z= 2,Dc= 1.357 g/cm3, Flack parameter = 0.10(3), R1(wR2) = 0.0697 (0.1702), andS= 1.086 for 4912 reflections withI> 2σ(I). Crystal data for2: C26H22N4O2,Mr= 422.48, monoclinic, space groupP21/n,a= 12.6296(17) Å,b= 6.1333(8) Å,c= 15.708(2) Å, β = 113.70(1)°,V= 1114.1(3) Å3,Z= 2,Dc= 1.259 g/cm3, R1(wR2) = 0.0460 (0.1215), andS= 0.979 for 1229 reflections withI> 2σ(I). CCDC-676026 (1) and 676027 (2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk/data_request/cif.
26. Blatov V. A. · Acta Crystallogr., Sect. A · 1995 · 51 · 90910.1107/S0108767395006799 ↗
27. Blatov V. A. · CrystEngComm · 2004 · 6 · 37710.1039/B409722J ↗