Phase Equilibria in the Zn-Rich Corner of the Zn-Cu-Ti-RE (Ce,La) Systems at 450 °C
Source abstract
Abstract
The Zn-rich corner of the Zn-Cu-Ti-RE(Ce, La) quaternary systems at 450 °C have been experimentally investigated by scanning electron microscopy coupled with energy dispersive x-ray spectrometer and x-ray diffraction. The liquid containing phase regions have been well identified in these two systems. The ternary compound τ (Cu2TiZn20) can equilibrate with all phases in the Zn-rich corner of these two systems. Neither Ce nor La can dissolve into TiZn16, e(CuZn4) and τ(Cu2TiZn20). While the solubility of Cu in CeZn11 and LaZn13 can reach 2.9 at.% and 5.0 at.%, respectively. The results can help to design and analyze the Zn-Cu-Ti-RE alloys.
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Research context
OpenAlex topics: Rare-earth and actinide compounds · Metallurgical and Alloy Processes · Intermetallics and Advanced Alloy Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (29)
Show source-provided references
1. M. Faur and B. Ghiban, Effects of Hot and Cold Rolling on the Microstructure of Low Alloy Zn-Cu and Zn-Cu-Ti Zinc Alloy with Improved Corrosion Resistance, Metall. Int., 2009, 14(3), p 23-26
2. H. Kaya, E. Çadırlı, and A. Ülgen, Investigation of the Effect of Composition on Microhardness and Determination of Thermo-Physical Properties in the Zn-Cu Alloys, Mater. Des., 2011, 32(2), p 900-90610.1016/j.matdes.2010.06.049 ↗
3. T. Savaşkan, A.P. Hekimoğlu, and G. Pürçek, Effect of Copper Content on the Mechanical and Sliding Wear Properties of Monotectoid-Based Zinc-Aluminium-Copper Alloys, Tribol. Int., 2004, 37(1), p 45-5010.1016/S0301-679X(03)00113-0 ↗
4. X.-Q. Xu, D.-F. Li, S.-L. Guo, and X.-P. Wu, Microstructure Evolution of Zn-8Cu-0.3Ti Alloy During Hot Deformation, Trans. Nonferr. Met. Soc., 2012, 22(7), p 1606-161210.1016/S1003-6326(11)61363-0 ↗
5. Y. Sheng, S.-H. Liang, K.-X. Song, and Q. Wang, Corrosion and Electrochemical Behavior of Zn-Cu-Ti Alloy Added with La in 3% NaOH Solution, J. Wuhan Univ. Technol., 2016, 31(2), p 408-41610.1007/s11595-016-1384-x ↗
6. J.-L. Bu, P.-C. Wang, L.-Q. Ai, X.-M. Sang, and Y.-G. Li, High Temperature Creep Behavior of Zn-1.0Cu-0.2Ti Alloy, Adv. Mater. Res., 2011, 287-290, p 769-77610.4028/www.scientific.net/AMR.287-290.769 ↗
7. S. Ji, S. Liang, K. Song, H. Li, and Z. Li, Evolution of Microstructure and Mechanical Properties in Zn-Cu-Ti Alloy During Severe Hot Rolling at 300 °C, J. Mater. Res., 2017, 32(16), p 3146-315510.1557/jmr.2017.275 ↗
8. S.-Y. Ji, S.-H. Liang, K.-X. Song, and Q. Wang, Effect of La on Microstructure and Mechanical Properties of Zn-Cu-Ti Alloy, Chin. J. Nonferr. Met., 2016, 26(8), p 1649-1658
9. L.-R. Xiao, X.-M. Zhang, and Y. Wang, Static Recrystallization Behavior of Zn-1.0Cu-0.2Ti Alloy, Chin. J. Nonferr. Met., 2011, 21(11), p 2775-277910.1016/S1003-6326(11)61036-4 ↗
10. Z. Zermout, M. Durand-Charre, G. Kapelski, and B. Baudelet, Phase Equilibria in the Zn-Rich Corner of the Zn-Cu-Ti System, Z. Metallkd., 1996, 87(4), p 274-279
11. C. Wu, C. Zhu, X. Su, Y. Liu, H. Peng, and J. Wang, Thermodynamical and Kinetic Investigation of Formation of Periodic Layered Structure in TiCu/Zn Interface Reaction, Acta Metall. Sin., 2014, 50(8), p 930-936
12. V. Pavlyuk, W. Prochwicz, P. Solokha, O. Zelinska, B. Marciniak, and E. Różycka-Sokołowska, Interaction of the Components in the Ce-Cu-Zn Ternary System at 200 °C, J. Alloys Compd., 2006, 407(1), p 226-23110.1016/j.jallcom.2005.06.057 ↗
13. S. Fan, C. Wu, Y. Liu, H. Tu, X. Su, and J. Wang, 600 and 450°C Isothermal Sections of the Zn-Ce-Ti System, J. Alloys Compd., 2017, 709, p 842-84910.1016/j.jallcom.2017.03.215 ↗
14. C. Wu, S. Fan, H. Peng, Y. Liu, X. Su and J. Wang, 600 and 450 °C Isothermal Sections of the Zn-Ti-La System. Metall. Trans. A., Under review.
15. S.-M. Liang, H.-M. Hsiao, and R. Schmid-Fetzer, Thermodynamic Assessment of the Al-Cu-Zn System, part I: Cu-Zn Binary System, Calphad, 2015, 51, p 224-23210.1016/j.calphad.2015.09.010 ↗
16. J. Murray, The Ti-Zn (Titanium-Zinc) System, J. Phase Equilib., 1984, 5(1), p 52-56
17. A. Berche, M.-C. Record, and J. Rogez, Critical Review of the La-Zn System, Open Thermodyn. J., 2009, 3, p 7-1610.2174/1874396X00903010007 ↗
18. A. Berche, P. Benigni, J. Rogez, and M.-C. Record, Thermodynamic Assessment of the La-Zn System, Calphad, 2012, 36, p 65-7010.1016/j.calphad.2011.11.004 ↗
19. Z. Zhu and A.D. Pelton, Critical Assessment and Optimization of Phase Diagrams and Thermodynamic Properties of RE-Zn Systems-Part I: Sc-Zn, La-Zn, Ce-Zn, Pr-Zn, Nd-Zn, Pm-Zn and Sm-Zn, J. Alloys Compd., 2015, 641, p 249-26010.1016/j.jallcom.2015.03.140 ↗
20. C.P. Wang, X. Chen, X.J. Liu, F.S. Pan, and K. Ishida, Thermodynamic Modeling of the Ce-Zn and Pr-Zn Systems, J. Alloys Compd., 2008, 458(1-2), p 166-17310.1016/j.jallcom.2007.03.120 ↗
21. Z. Malik, O. Sologub, G. Giester, and P. Rogl, The System Ce-Zn-B at 800 °C, J. Solid State Chem., 2011, 184(11), p 2840-284810.1016/j.jssc.2011.08.020 ↗
22. T.B. Massalski, Binary Alloy Phase Diagrams, 2nd ed., ASM International, Materials Park, OH, 1990
23. H. Peng, Z. Li, X. Wang, J. Wang, Y. Liu, C. Wu, L. Li, and X. Su, 450 °C Isothermal Section of the Zn-Fe-Cu Ternary System, J. Phase Equilib. Diffus., 2011, 32(6), p 478-48510.1007/s11669-011-9948-0 ↗
24. Z. Liu, D. Qiu, F. Wang, J.A. Taylor, and M. Zhang, Crystallography of Grain Refinement in Cast Zinc-Copper Alloys, J. Appl. Crystallogr., 2015, 48(3), p 890-90010.1107/S1600576715008936 ↗
25. T.B. Massalski and H.W. King, The Lattice Spacing Relationships in H.C.P. ϵ and η Phases in the Systems Cu-Zn, Ag-Zn; Au-Zn and Ag-Cd, Acta Metall., 1962, 10(12), p 1171-118110.1016/0001-6160(62)90170-0 ↗
26. M. Saillard, G. Develey, C. Becle, J. Moreau, and D. Paccard, The Structure of TiZn16, Acta Crystallogr. B, 1981, 37(1), p 224-22610.1107/S0567740881002574 ↗
27. X.-A. Chen, W. Jeitschko, M.E. Danebrock, C.B.H. Evers, and K. Wagner, Preparation, Properties, and Crystal Structures of Ti3Zn22 and TiZn16, J. Solid State Chem., 1995, 118(2), p 219-22610.1006/jssc.1995.1337 ↗
28. A. Iandelli and A. Palenzona, Zinc-Rich Phases of the Rare-Earth-Zinc Alloys, J. Less Common Met., 1967, 12(5), p 333-34310.1016/0022-5088(67)90001-X ↗
29. C. Wu, L. Lu, J. Wang, X. Su, H. Tu, and H. Peng, Experimental Investigation and Thermodynamic Calculation of the Zn-Fe-La System, J. Alloys Compd., 2016, 654, p 264-27210.1016/j.jallcom.2015.09.080 ↗