journal article·2001-11-01

Dispersion Behaviors of Copper Oxide on the Mixed “CeO2+ γ-Al2O3” Support

L. Dong, Y. Hu, M. Shen, T. Jin, J. Wang, W. Ding, Y. Chen

Chemistry of Materials· Volume 13· Issue 11
Publisher page

Abstract

The dispersion behaviors of copper oxide on the mechanical mixture of CeO 2 and γ-Al 2 O 3 supports, CuO/CeO 2 + γ-Al 2 O 3, have been characterized by using XRD, LRS, XPS, UV-DRS, and TPR. The results show that copper oxide dispersed mainly on the surface of CeO 2 support, provided that the loading amount of copper oxide does not exceed the dispersion capacity of CuO/CeO 2, ∼1.2 mmol of CuO/100 m 2 of CeO 2 (Dong, L.; Jin, Y. S.; Chen, Y. Sci. China (B). 1997, 40, 24). Increasing the CuO loading evidently leads to the formation of the dispersed copper oxide species on the surface of the γ-Al 2 O 3 support. The results have been tentatively discussed by using the incorporation model, which was proposed to describe the interaction between the dispersed species and the support previously (Chen, Y.; Zhang, L. F. Catal. Lett. 1992, 12, 51).
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Catalytic Processes in Materials Science · Catalysis and Oxidation Reactions · Magnesium Oxide Properties and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Laboratory of Mesoscopic Materials and Chemistry, Nanjing University, Nanjing, 210093, China

References (37)

Show source-provided references
1. Arias A. M. · Catal. Lett. · 2000 · 65 · 19710.1023/A:1019089910238 ↗
2. Fally F. · Catal. Today. · 2000 · 59 · 37310.1016/S0920-5861(00)00302-3 ↗
3. Ozaki T. · Chem. Mater. · 2000 · 12 · 64310.1021/cm9903374 ↗
4. Davis R. J. · Chem. Mater. · 1997 · 9 · 231110.1021/cm970314u ↗
5. Yoshida H. · Stud. Surf. Sci. Catal. · 2000 · 130 · 65910.1016/S0167-2991(00)81033-2 ↗
6. Koningsberger D. C. · Stud. Surf. Sci. Catal. · 2000 · 130 · 31710.1016/S0167-2991(00)80976-3 ↗
7. Powell Q. H. · Chem. Mater. · 1997 · 9 · 68510.1021/cm960334g ↗
8. Klimova T. · Stud. Surf. Sci. Catal. · 2000 · 130 · 280110.1016/S0167-2991(00)80895-2 ↗
9. Cedeno L. · Stud. Surf. Sci. Catal. · 2000 · 130 · 280710.1016/S0167-2991(00)80896-4 ↗
10. Taylor · 1986
11. Knozinger H. · Adv. Catal. · 1976 · 25 · 18410.1016/S0360-0564(08)60315-6 ↗
12. Lin P. Y. · Appl. Catal. B-Env. · 1995 · 6 · 23710.1016/0926-3373(95)00008-9 ↗
13. Dong L. · J. Phys. Chem. · 2000 · 104 · 7810.1021/jp9914424 ↗
14. Chen Y. · Stud. Surf. Sci. Catal. · 1996 · 101 · 129310.1016/S0167-2991(96)80341-7 ↗
15. Hu Y. H. · J. Mol. Catal. (A, Chem.) · 2000 · 162 · 30710.1016/S1381-1169(00)00299-5 ↗
16. Kermidas V. G. · J. Phys. Chem. · 1973 · 59 · 156110.1063/1.1680227 ↗
17. Mestaland G. · 1997 · 2
18. Larsson P. O. · J. Catal. · 1996 · 163 · 27910.1006/jcat.1996.0329 ↗
19. Larsson P. O. · J. Catal. · 1998 · 179 · 7210.1006/jcat.1998.2198 ↗
20. Busca G. · Catal. Today · 1994 · 20 · 6110.1016/0920-5861(94)85016-X ↗
21. Kobayashi H. · Stud. Surf. Sci. Catal. · 1983 · 16 · 69710.1016/S0167-2991(09)60060-4 ↗
22. Shyu J. Z. · J. Phys. Chem. · 1988 · 92 · 496410.1021/j100328a029 ↗
23. Knozinger H. · 1993 · 10
24. Wachs I. E. · Catal. Today · 1996 · 27 · 43710.1016/0920-5861(95)00203-0 ↗
25. Lo Jacono M. · J. Phys. Chem. · 1971 · 75 · 104410.1021/j100678a005 ↗
26. Wu M. · J. Phys. Chem. · 1979 · 83 · 200310.1021/j100478a015 ↗
27. Burggaf L. W. · J. Catal. · 1982 · 78 · 36010.1016/0021-9517(82)90320-7 ↗
28. Chen Y. · Catal. Sci. Technol. · 1991 · 1 · 291
29. Chen Y. · Catal. Lett. · 1992 · 12 · 5110.1007/BF00767188 ↗
30. Cochrane H. D. · Ultramicroscopy · 1989 · 31 · 13810.1016/0304-3991(89)90044-2 ↗
31. Dong L. · J. Chem. Soc., Faraday Trans. · 1996 · 92 · 458910.1039/ft9969204589 ↗
32. Beaufils P. · J. Chim. Phys. · 1981 · 78 · 34710.1051/jcp/1981780347 ↗
33. Jimenez-Conzalez J. · Surf. Sci. · 1991 · 250 · 5910.1016/0039-6028(91)90709-2 ↗
34. Tench A. J. · Trans. Faraday Soc. · 1967 · 63 · 225410.1039/tf9676302254 ↗
35. Che M. · J. Catal. · 1972 · 24 · 32810.1016/0021-9517(72)90077-2 ↗
36. Seyle T. X. T. · J. Chem. Soc., Chem. Commun. · 1992 · 997
37. Xia W. S. · J. Mol. Catal., A · 1999 · 138 · 18510.1016/S1381-1169(98)00145-9 ↗