Lanthanide Complexes with 2-(Tosylamino)-benzylidene-N-(aryloyl)hydrazones: Universal Luminescent Materials

Anton Kovalenko; Pavel O. Rublev; Lyubov O. Tcelykh; Alexander S. Goloveshkin; Leonid S. Lepnev; Anatolii S. Burlov; Andrey A. Vashchenko; Łukasz Marciniak; Abel M. Magerramov; Namig G. Shikhaliyev; Sergey Z. Vatsadze; Valentina V. Utochnikova

doi:10.1021/acs.chemmater.8b03675

journal article·2019-02-12

Lanthanide Complexes with 2-(Tosylamino)-benzylidene-N-(aryloyl)hydrazones: Universal Luminescent Materials

Anton Kovalenko, Pavel O. Rublev, Lyubov O. Tcelykh, Alexander S. Goloveshkin, Leonid S. Lepnev, Anatolii S. Burlov, Andrey A. Vashchenko, Łukasz Marciniak, Abel M. Magerramov, Namig G. Shikhaliyev, Sergey Z. Vatsadze, Valentina V. Utochnikova

Chemistry of Materials· Volume 31· Issue 3

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Source abstract

Abstract

Lanthanide complexes Ln(L1)(HL1) (Ln = Lu, Yb, Er, Gd, Eu, Sm) and Ln(L2)(HL2) (Ln = Lu, Yb, Gd, Eu) with 2-(tosylamino)-benzylidene-N-(aryloyl)hydrazones (H2L1, aryloyl = 2-hydroxybenzoyl; H2L2, aryloyl = isonicotinoyl) were obtained with the aim to explore them as new luminescent materials. They were found to form monomeric species independently on the aryloyl group, and their crystal structures were determined from single-crystal X-ray data (Yb(L2)(HL2)·0.5(C2H5OH)), as well as from powder X-ray data by Rietveld refinement (Eu(L1)(HL1)). Ytterbium complexes exhibited intense luminescence, which allowed using them in host-free organic light-emitting diodes, which demonstrated remarkable efficiency of near infrared electroluminescence (50 μW/W) at low voltage (5 V). The special mechanism of europium luminescence quenching allowed using europium complexes as luminescent thermometers, which demonstrated very high sensitivity up to 12%/K. The theory of luminescence thermometry based on a three-level system was proposed, which allowed predicting sensitivity with high accuracy (error within 20%).

Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Lanthanide and Transition Metal Complexes · Magnetism in coordination complexes · Luminescence Properties of Advanced Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Faculty of Chemistry, Lomonosov Moscow State University, GSP-1, 1-3 Leninskiye Gory, 119991 Moscow, Russia

Centre de Biophysique Moléculaire—UPR 4301, Center National De La Recherche Scientifique, Rue Charles Sadron, Orléans 45071, France

A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, GSP-1, Vavilova Street 28, 119991 Moscow, Russia

Lebedev Physical Institute, Russian Academy of Sciences, GSP-1, Leninsky Avenue 53, 119991 Moscow, Russia

Institute of Physical & Organic Chemistry, Southern Federal University, Stachka Avenue, 194/2, 344090 Rostov-on-Don, Russia

Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P Nr 1410, 50-950 Wrocław 2, Poland

Faculty of Chemistry, Baku State University, Academic Zahid Xalilov Street, 23, Baku AZ 1148, Azerbaijan

SIA Evoled, 1a-24 Puskina iela, LV-1050 Riga, Latvia

Funding

Russian Science Foundation · Russian Foundation for Basic Research

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