Nitrogen Doping of Ceria
Source abstract
Abstract
Incorporation of nitrogen into the fluorite structure of ceria occurs by treatment in ammonia between 550 and 900 °C, with maximum uptake of 4.5 mol % N at temperatures close to 700 °C and with reduction to Ce3+ above 650 °C, leading to the solid solution Ce4+1−yCe3+yO2–(3x/2)−(y/2)NxV(x+y)/2 with x ≤ 0.09 and y ≤ 0.03.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Catalytic Processes in Materials Science · Advancements in Solid Oxide Fuel Cells · Nuclear materials and radiation effects
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institut de Ciència de Materials de Barcelona (CSIC), Campus U.A.B., 08193 Bellaterra, Spain, Instituto de Ciencia de Materiales, Universidad de Valencia, P.O. Box 22085, 46071 Valencia, Spain, and Centre for Science at Extreme Conditions and School of Chemistry, University of Edinburgh, King’s Buildings, Mayfield Road, Edinburgh EH9 3JZ, United Kingdom
References (31)
Show source-provided references
1. Asahi R. · Science · 2001 · 293 · 26910.1126/science.1061051 ↗
2. Hitoki G. · Chem. Commun. · 2002 · 169810.1039/B202393H ↗
3. Jansen M. · Nature · 2000 · 404 · 98010.1038/35010082 ↗
4. Cheng Y. · J. Am. Ceram. Soc. · 1993 · 76 · 68310.1111/j.1151-2916.1993.tb03660.x ↗
5. Wendel J. · J. Solid State Chem. · 1999 · 142 · 16310.1006/jssc.1998.8013 ↗
6. Lee J. · J. Solid State Chem. · 2006 · 179 · 27010.1016/j.jssc.2005.10.012 ↗
7. Inaba H. · Solid State Ionics · 1996 · 83 · 110.1016/0167-2738(95)00229-4 ↗
8. Feng X. D. · Science · 2006 · 312 · 150410.1126/science.1125767 ↗
9. Deluga G. A. · Science · 2004 · 303 · 99310.1126/science.1093045 ↗
10. Corma A. · Nat. Mater. · 2004 · 3 · 39410.1038/nmat1129 ↗
11. Fuertes, A.; Jorge, A. B.Patent Application number 200700482, Spanish Patent and Trademark Office, Spain, February 2007.
12. Zhou K. · Chem. Mater. · 2007 · 19 · 121510.1021/cm062886x ↗
13. Wu L. · Phys. Rev. B · 2004 · 69 · 12541510.1103/PhysRevB.69.125415 ↗
14. Esch F. · Science · 2005 · 309 · 75210.1126/science.1111568 ↗
15. Shah P. R. · Chem. Mater. · 2006 · 18 · 536310.1021/cm061374f ↗
16. Jobbágy M. · Chem. Mater. · 2006 · 18 · 194510.1021/cm052437h ↗
17. Dutta P. · Chem. Mater. · 2006 · 18 · 514410.1021/cm061580n ↗
18. Brown R. C. · J. Inorg. Nucl. Chem. · 1974 · 36 · 177710.1016/0022-1902(74)80510-5 ↗
19. Barker M. G. · J. Chem. Soc., Dalton Trans. · 1974 · 216610.1039/dt9740002166 ↗
20. Martínez-Ferrero E. · Adv. Funct. Mater. · 2007 · 17 · 334810.1002/adfm.200700396 ↗
21. Chen H. · J. Phys. Chem. C · 2007 · 111 · 136610.1021/jp066137e ↗
22. Gilles J. C. · Bull. Soc. Chim. Fr. · 1962 · 22 · 2118
23. Collongues R. · Mater. Res. Bull. · 1967 · 2 · 83710.1016/0025-5408(67)90092-X ↗
24. Rodríguez-Carvajal J. · Physica B · 1993 · 192 · 5510.1016/0921-4526(93)90108-I ↗
25. Shanon R. D. · Acta Crystallogr., Sect. A · 1976 · 32 · 75110.1107/S0567739476001551 ↗
26. Bevan D. J. M. · J. Inorg. Nucl. Chem. · 1964 · 26 · 150910.1016/0022-1902(64)80038-5 ↗
27. Brauer G. · J. Inorg. Nucl. Chem. · 1960 · 16 · 8710.1016/0022-1902(60)80091-7 ↗
28. Saha N. C. · J. Appl. Phys. · 1992 · 72 · 307210.1063/1.351465 ↗
29. Xiao S. Q. · Thin Solid Films · 1998 · 317 · 13710.1016/S0040-6090(97)00610-X ↗
30. Webber W. H. · Phys. Rev. B · 1993 · 48 · 17810.1103/PhysRevB.48.178 ↗
31. Dohcevic-Mitrovic Z. D. · Solid State Commun. · 2006 · 13 · 38710.1016/j.ssc.2005.12.006 ↗