A Nanostructured, Scandium-Containing Polymer for Heterogeneous Lewis Acid Catalysis in Water
Source abstract
Abstract
A nanostructured, polymer-supported Sc(III) catalyst for heterogeneous Lewis acid catalysis in water was prepared by quantitative Sc(III) exchange of a cross-linked inverted hexagonal assembly containing sodium sulfonate groups. The material was found to catalyze Mukaiyama aldol and Mannich reactions with a syn/anti product ratio of ca. 2/1, whereas Sc(III) catalysts in solution and on amorphous polymer supports do not show any significant syn/anti diastereoselectivity under similar conditions.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Mesoporous Materials and Catalysis · Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, University of California, Berkeley, California 94720-1460
References (19)
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