journal article·2012-05-22

Growth Mechanism of Single-Walled Carbon Nanotubes on Iron–Copper Catalyst and Chirality Studies by Electron Diffraction

Maoshuai He, Bilu Liu, Alexander I. Chernov, Elena D. Obraztsova, Inkeri Kauppi, Hua Jiang, Ilya Anoshkin, Filippo Cavalca, Thomas W. Hansen, Jakob B. Wagner, Albert. G. Nasibulin, Esko I. Kauppinen, Juha Linnekoski, Marita Niemelä, Juha Lehtonen

Chemistry of Materials· Volume 24· Issue 10
Publisher page

Abstract

Chiralities of single-walled carbon nanotubes grown on an atomic layer deposition prepared bimetallic FeCu/MgO catalyst were evaluated quantitatively using nanobeam electron diffraction. The results reveal that the growth yields nearly 90% semiconducting tubes, 45% of which are of the (6,5) type. The growth mechanisms as well as the roles of different components in the catalyst were studied in situ using environmental transmission electron microscopy and infrared spectroscopy. On the basis of the understanding of carbon nanotube growth mechanisms, an MgO-supported FeCu catalyst was prepared by impregnation, showing similar catalytic performance as the atomic layer deposition-prepared catalyst, yielding single-walled carbon nanotubes with a similar narrow chirality distribution.
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Research context

OpenAlex topics: Carbon Nanotubes in Composites · Graphene research and applications · Chemical and Physical Properties of Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Biotechnology and Chemical Technology, School of Chemical Technology, Aalto University, P.O. Box 16100, FI-00076 Aalto, Finland

NanoMaterials Group, Department of Applied Physics and Center for New Materials, School of Science, Aalto University, P.O. Box 15100, FI-00076 Aalto, Finland

Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, P. R. China

A. M. Prokhorov General Physics Institute RAS, 38 Vavilov Street, 119991 Moscow, Russia

Center for Electron Nanoscopy, Technical University of Denmark, DK-2800 Kgs Lyngby, Denmark

References (46)

Show source-provided references
1. Iijima S. · Nature · 1993 · 363 · 60310.1038/363603a0 ↗
2. Bethune D. S. · Nature · 1993 · 363 · 60510.1038/363605a0 ↗
3. Iijima S. · Nature · 1991 · 354 · 5610.1038/354056a0 ↗
4. Dresselhaus M. S. · Phys. Rep. · 2005 · 409 · 4710.1016/j.physrep.2004.10.006 ↗
5. Hersam M. C. · Nat. Nanotechnol. · 2008 · 3 · 38710.1038/nnano.2008.135 ↗
6. Noorden R. V. · Nature · 2011 · 469 · 1410.1038/469014a ↗
7. Wu Z. · Science · 2004 · 305 · 127310.1126/science.1101243 ↗
8. Tans S. J. · Nature · 1998 · 393 · 4910.1038/29954 ↗
9. Naumov A. V. · Nano Lett. · 2009 · 9 · 320310.1021/nl9014342 ↗
10. Liu Z. · Phys. Rev. B · 2005 · 71 · 24541310.1103/PhysRevB.71.245413 ↗
11. Arnold M. S. · Nat. Nanotechnol. · 2006 · 1 · 6010.1038/nnano.2006.52 ↗
12. Nish A. · Nat. Nanotechnol. · 2007 · 2 · 64010.1038/nnano.2007.290 ↗
13. Krupke R. · Science · 2003 · 301 · 34410.1126/science.1086534 ↗
14. Harutyunyan A. R. · Science · 2009 · 326 · 11610.1126/science.1177599 ↗
15. Li Y. · J. Phys. Chem. B · 2005 · 109 · 696810.1021/jp050868h ↗
16. Hong G. · J. Am. Chem. Soc. · 2009 · 131 · 1464210.1021/ja9068529 ↗
17. Wang H. · J. Am. Chem. Soc. · 2010 · 132 · 1674710.1021/ja106937y ↗
18. Bachilo S. M. · J. Am. Chem. Soc. · 2003 · 125 · 1118610.1021/ja036622c ↗
19. Ding L. · Nano Lett. · 2009 · 9 · 80010.1021/nl803496s ↗
20. Chiang W. H. · Nat. Mater. · 2009 · 8 · 88210.1038/nmat2531 ↗
21. Zhu Z. · J. Am. Chem. Soc. · 2011 · 133 · 122410.1021/ja1087634 ↗
22. Jorio A. · Phys. Rev. B · 2005 · 72 · 07520710.1103/PhysRevB.72.075207 ↗
23. Loebick C. Z. · J. Am. Chem. Soc. · 2010 · 132 · 1112510.1021/ja102011h ↗
24. He M. · J. Am. Chem. Soc. · 2010 · 132 · 1399410.1021/ja106609y ↗
25. Zuo J. M. · Science · 2003 · 300 · 141910.1126/science.1083887 ↗
26. Qin L. C. · Ultramicroscopy · 1997 · 67 · 18110.1016/S0304-3991(96)00095-2 ↗
27. Jiang H. · Carbon · 2007 · 45 · 66210.1016/j.carbon.2006.07.025 ↗
28. Ding F. · Proc. Natl. Acad. Sci. · 2009 · 106 · 250610.1073/pnas.0811946106 ↗
29. Wang Q. · ACS Nano · 2010 · 4 · 93910.1021/nn901761u ↗
30. Hu Y. H. · Catal. Rev. · 2002 · 44 · 42310.1081/CR-120005742 ↗
31. Cordischi D. · J. Phys. Chem. · 1973 · 77 · 124010.1021/j100629a012 ↗
32. Wielers A. H. F. · J. Catal. · 1990 · 121 · 37510.1016/0021-9517(90)90246-G ↗
33. de Smit E. · Phys. Chem. Chem. Phys. · 2010 · 12 · 66710.1039/B920256K ↗
34. Wachs I. E. · Appl. Catal. · 1984 · 12 · 20110.1016/S0166-9834(00)80291-2 ↗
35. Talapatra S. · Nat. Nanotechnol. · 2006 · 1 · 11210.1038/nnano.2006.56 ↗
36. Wang H. · J. Phys. Chem. C · 2007 · 111 · 1261710.1021/jp0730848 ↗
37. Lin W. · IEEE Trans. Adv. Packag. · 2010 · 33 · 37010.1109/TADVP.2009.2034335 ↗
38. Hofmann S. · Nano Lett. · 2007 · 7 · 60210.1021/nl0624824 ↗
39. Yoshida H. · Nano Lett. · 2008 · 8 · 208210.1021/nl080452q ↗
40. Li Q. W. · J. Mater. Chem. · 2002 · 12 · 117910.1039/b109763f ↗
41. Lolli G. · J. Phys. Chem. B · 2006 · 110 · 210810.1021/jp056095e ↗
42. Davydov A. · 200310.1002/0470867981 ↗
43. Wasylenko W. · Phys. Chem. Chem. Phys. · 2007 · 9 · 549710.1039/b706689a ↗
44. Astakhova T. Y. · Fullerene Sci. Technol. · 1999 · 7 · 22310.1080/10641229909350281 ↗
45. He M. · Chem. Commun. · 2011 · 47 · 121910.1039/C0CC02751K ↗
46. He M. · Nano Res. · 2011 · 4 · 33410.1007/s12274-010-0088-3 ↗