journal article·2007-01-01

Cs+-Selective Ion Exchange and Magnetic Ordering in a Three-Dimensional Framework Uranyl Vanadium(IV) Phosphate

Tatiana Y. Shvareva, S. Skanthakumar, L. Soderholm, Abraham Clearfield, Thomas E. Albrecht-Schmitt

Chemistry of Materials· Volume 19· Issue 2
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Abstract

A three-dimensional framework uranyl vanadium(IV) phosphate, K3.48[(UO2)(VO)4H1.52(PO4)5], has been prepared by hydrothermal methods and structurally characterized. The K+ cations in this compound can be selectively exchanged with Cs+. This compound also undergoes antiferromagnetic ordering at 52(2) K.
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Research context

OpenAlex topics: Radioactive element chemistry and processing · Chemical Synthesis and Characterization · Crystal Structures and Properties

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Affiliations

Department of Chemistry and Biochemistry and E. C. Leach Nuclear Science Center, Auburn University, Auburn, Alabama 36849, Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, Texas A&M University, College Station, Texas 77842

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