Missing Piece of the Mechanism of the Turkevich Method: The Critical Role of Citrate Protonation
Source abstract
Abstract
This contribution investigates the growth mechanism of the Turkevich method. The experimental results provide the missing piece of the mechanistic puzzle which enables the actual control of particle growth in the commonly used Turkevich method. Applying the gained knowledge, the boundary conditions for a successful Turkevich synthesis are deduced. Moreover, the conditions under which the Turkevich method is highly reproducible are derived. Following these conditions, the Turkevich synthesis is modified to reveal small monodisperse particles with an unprecedented reproducibility of ±0.1 nm.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Iron oxide chemistry and applications · Coagulation and Flocculation Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489 Berlin, Germany
Technische Universität Berlin, Straße des 17. Juni 124, 10623 Berlin, Germany
Funding
Bundesministerium für Bildung und Forschung · Deutsche Forschungsgemeinschaft · Einstein Stiftung Berlin · International Max Planck Research School Functional Interfaces in Physics and Chemistry
References (31)
Show source-provided references
1. 10.1016/j.ccr.2012.09.00210.1016/j.ccr.2012.09.002 ↗
2. 10.1007/s11468-011-9228-110.1007/s11468-011-9228-1 ↗
3. 10.1039/df951110005510.1039/df9511100055 ↗
4. Hauser E. A. · 1940
5. 10.1002/adma.20070318310.1002/adma.200703183 ↗
6. 10.1021/ja074447k10.1021/ja074447k ↗
7. 10.1021/jp201724210.1021/jp2017242 ↗
8. 10.1007/s13404-012-0069-210.1007/s13404-012-0069-2 ↗
9. 10.1021/acsnano.5b0157910.1021/acsnano.5b01579 ↗
10. 10.1021/la503209b10.1021/la503209b ↗
11. 10.1021/ja906506j10.1021/ja906506j ↗
12. 10.1039/C5CE01014D10.1039/C5CE01014D ↗
13. 10.1021/ja980542510.1021/ja9805425 ↗
14. 10.1021/j100317a03210.1021/j100317a032 ↗
15. 10.1021/jp305830p10.1021/jp305830p ↗
16. 10.1016/0016-7037(91)90332-Y10.1016/0016-7037(91)90332-Y ↗
17. 10.1016/S0927-7757(98)00790-010.1016/S0927-7757(98)00790-0 ↗
18. 10.1021/jp811296m10.1021/jp811296m ↗
19. 10.1016/S0010-8545(00)82022-610.1016/S0010-8545(00)82022-6 ↗
20. 10.1021/ja01331a07110.1021/ja01331a071 ↗
21. 10.1016/0040-6031(86)87081-210.1016/0040-6031(86)87081-2 ↗
22. 10.1021/ie060672j10.1021/ie060672j ↗
23. 10.1016/j.matchemphys.2007.09.00110.1016/j.matchemphys.2007.09.001 ↗
24. 10.1016/j.jcis.2011.06.01510.1016/j.jcis.2011.06.015 ↗
25. 10.1016/j.jcis.2013.02.04010.1016/j.jcis.2013.02.040 ↗
26. 10.1039/c2nr30957b10.1039/c2nr30957b ↗
27. 10.1039/C5CP02219C10.1039/C5CP02219C ↗
28. 10.1016/j.jcat.2005.01.03010.1016/j.jcat.2005.01.030 ↗
29. 10.1016/0016-7037(91)90340-B10.1016/0016-7037(91)90340-B ↗
30. 10.1016/j.jelechem.2005.12.02010.1016/j.jelechem.2005.12.020 ↗
31. 10.1039/c0cc03238g10.1039/c0cc03238g ↗