journal article·2011-10-25

Low Temperature Growth of High Purity, Low Resistivity Copper Films by Atomic Layer Deposition

Thomas J. Knisley, Thiloka C. Ariyasena, Timo Sajavaara, Mark J. Saly, Charles H. Winter

Chemistry of Materials· Volume 23· Issue 20
Publisher page

Abstract

The atomic layer deposition of copper metal thin films was achieved using a three precursor sequence entailing Cu(OCHMeCH2NMe2)2, formic acid, and hydrazine. A constant growth rate of 0.47−0.50 Å/cycle was observed at growth temperatures between 100 and 170 °C. The resulting films are high purity and have low resistivities.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Semiconductor materials and devices · Copper Interconnects and Reliability · Advanced Memory and Neural Computing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Wayne State University, Detroit, Michigan 48202, United States

Department of Physics, University of Jyväskylä, 40014 Jyväskylä, Finland,

SAFC Hitech, 1429 Hilldale Avenue, Haverhill, Massachusetts 01832, United States

References (29)

Show source-provided references
1. Kim H. · Surf. Coat. Technol. · 2006 · 200 · 310410.1016/j.surfcoat.2005.07.006 ↗
2. International Technology Roadmap for Semiconductors,http://www.itrs.net/.
3. Leskelä M. · Angew. Chem., Int. Ed. · 2003 · 42 · 554810.1002/anie.200301652 ↗
4. Lee B. H. · Angew. Chem., Int. Ed. · 2009 · 48 · 453610.1002/anie.200900414 ↗
5. Vidjayacoumar B. · Chem. Mater. · 2010 · 22 · 484410.1021/cm101442e ↗
6. Hsu I. J. · J. Vac. Sci. Technol., A · 2009 · 27 · 66010.1116/1.3143663 ↗
7. Lim B. S. · Nat. Mater. · 2003 · 2 · 748
8. Li Z. · J. Electrochem. Soc. · 2006 · 153 · C78710.1149/1.2338632 ↗
9. Li Z. · Electrochem. Solid-State Lett. · 2005 · 8 · G18210.1149/1.1924929 ↗
10. Solanki R. · Electrochem. Solid-State Lett. · 2000 · 3 · 47910.1149/1.1391185 ↗
11. Mårtensson P. · Chem. Vap. Deposition · 1997 · 3 · 4510.1002/cvde.19970030107 ↗
12. Juppo M. · J. Vac. Sci. Technol., A · 1997 · 15 · 233010.1116/1.580743 ↗
13. Park K.-H. · Inorg. Chem. · 2006 · 45 · 848010.1021/ic061016e ↗
14. Thompson J. S. · Thin Solid Films · 2009 · 517 · 284510.1016/j.tsf.2008.10.067 ↗
15. Huo J. · J. Mater. Res. · 2002 · 17 · 239410.1557/JMR.2002.0350 ↗
16. Li Z. · Chem. Vap. Deposition · 2006 · 12 · 43510.1002/cvde.200606485 ↗
17. Waechtler T. · Microelectron. Eng. · 2011 · 88 · 68410.1016/j.mee.2010.07.004 ↗
18. Niskanen A. · J. Electrochem. Soc. · 2005 · 152 · G2510.1149/1.1824046 ↗
19. Moon D.-Y. · Thin Solid Films · 2011 · 519 · 363610.1016/j.tsf.2011.01.346 ↗
20. Goel S. C. · Polyhedron · 1990 · 9 · 61110.1016/S0277-5387(00)86241-5 ↗
21. Becker R. · Chem. Vap. Deposition · 2003 · 9 · 14910.1002/cvde.200306236 ↗
22. Ravindranathan P. · Thermochim. Acta · 1983 · 71 · 5310.1016/0040-6031(83)80354-2 ↗
23. Handbook of X-ray Photoelectron Spectroscopy;Wagner, C. D.; Riggs, W. M.; Davis, L. E.; Moulder, J. F.; Murlenberg, G. E., Eds.Perkin-Elmer Corporation:Eden Prairie, MN; 1979, pp81,82.
24. Barnat E. V. · J. Appl. Phys. · 2002 · 91 · 166710.1063/1.1430530 ↗
25. CRC Handbook of Chemistry and Physics,91sted.Haynes, W. M., Ed. CRC Press: 2010–2011; pp8-20,8-29.
26. Song H. · Microelectronics Eng. · 2010 · 87 · 24910.1016/j.mee.2009.07.017 ↗
27. CRC Handbook of Chemistry and Physics;91sted.Haynes, W. M., Ed. CRC Press: 2010–2011; pp8–45.
28. Aaltonen T. · J. Mater. Res. · 2004 · 19 · 335310.1557/JMR.2004.0426 ↗
29. Knapas K. · Chem. Mater. · 2011 · 23 · 276610.1021/cm103490v ↗