journal article·2006-01-01

Individualized Single Walled Carbon Nanotubes from Bulk Material Using 96% Sulfuric Acid as Solvent

Jason J. Stephenson, Jared L. Hudson, Samina Azad, James M. Tour

Chemistry of Materials· Volume 18· Issue 2
Publisher page

Abstract

Single walled carbon nanotubes (SWNTs) have been functionalized in a mixture of 96% sulfuric acid and ammonium persulfate, using sodium nitrite to produce intermediate diazonium salts from substituted anilines. These afford unbundled functionalized SWNTs from bulk bundled SWNTs. This new process eliminates the need for corrosive and more expensive oleum solvent, as described in prior work, and therefore also reduces the formation of sulfonated products.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Carbon Nanotubes in Composites · Graphene research and applications · Fullerene Chemistry and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Departments of Chemistry and Mechanical Engineering and Materials Science, and Center for Nanoscale Science and Technology, Rice University, MS 222, 6100 Main Street, Houston, Texas 77005

References (15)

Show source-provided references
1. Bahr J. L. · J. Am. Chem. Soc. · 2001 · 123 · 6542
2. Bahr J. L. · Chem. Mater. · 2001 · 13 · 3824
3. Dyke C. A. · J. Am. Chem. Soc. · 2003 · 125 · 1157
4. Dyke C. A. · Nano Lett. · 2003 · 3 · 1218
5. Liang F. · Nano Lett. · 2004 · 4 · 126010.1021/nl049428c ↗
6. Davis V. A. · Macromolecules · 2004 · 37 · 160
7. Hudson J. L. · J. Am. Chem. Soc. · 2004 · 126 · 1115910.1021/ja0467061 ↗
8. Dyke C. A. · J. Phys. Chem. A. · 2005 · 108 · 11159
9. Davis, V. A. Ph.D. Dissertation, Rice University, 2005, p 140.10.1576/toag.7.2.140.27079 ↗
10. Chiang J. U.S. · 1977
11. Dyke C. A. · Synlett · 2004 · 155 · 160
12. Ziegler K. J. · J. Am. Chem. Soc · 2005 · 12710.1021/ja044537e ↗
13. Dyke C. A. · Chem. Eur. J. · 2004 · 10 · 817
14. Weisman R. B. · 2004
15. Sadana A. K. · J. Phys. Chem. B. · 2005 · 109 · 441810.1021/jp045582b ↗