Changes in Electronic Structure between Cobalt and Oxide Ions of Lithium Cobalt Phosphate as 4.8-V Positive Electrode Material
Source abstract
Abstract
Insight into electron exchange in LiCoPO4 electrodes for high-voltage lithium ion battery is presented using X-ray absorption spectroscopy (XAS). Despite the formation of the isolated valence electrons around the Co ion, O K-edge XAS reveals clear evidence that the hybridized orbital between Co and O plays an important role in the electron exchange arising from the electrochemical Li extraction.
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research
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Affiliations
Department of Applied Chemistry, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8552, Japan, and Photon Factory, Institute of Materials Structure Science, High Energy Accelerator Research Organization, 1-1 Oho, Tsukuba, Ibaraki 305-0801, Japan
References (10)
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