journal article·2006-07-01

A Novel Approach to Monodisperse, Luminescent Silica Spheres

Adam M. Jakob, Thomas A. Schmedake

Chemistry of Materials· Volume 18· Issue 14
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Abstract

Monodisperse aminopropylsilica spheres were grown via a modified Stöber process with varying amounts of tetraethyl orthosilicate and (aminopropyl)triethoxysilane (APTES). Upon calcination, the spheres become luminescent, with the emission maximum dependent on the original APTES concentration. This provides a simple one-step route to gram-scale quantities of tailorable, luminescent, monodisperse silica spheres.
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Research context

OpenAlex topics: Mesoporous Materials and Catalysis · Diatoms and Algae Research · Photonic Crystals and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, University of North Carolina, Charlotte, NC 28223

References (17)

Show source-provided references
1. Yoldas B. E. · J. Mater. Res. · 1990 · 5 · 115710.1557/JMR.1990.1157 ↗
2. Green W. H. · J. Science · 1997 · 276 · 1826
3. Stöber W. · J. Colloid Interface Sci. · 1968 · 26 · 6210.1016/0021-9797(68)90272-5 ↗
4. van Blaaderen A. · Langmuir · 1992 · 8 · 292110.1021/la00048a013 ↗
5. Sloof L. H. · Appl. Phys. Lett. · 2000 · 76 · 368210.1063/1.126748 ↗
6. Zhao D. · Chem. Phys. Lett. · 2004 · 388 · 40010.1016/j.cplett.2004.03.037 ↗
7. Chan Y. · Adv. Mater. · 2004 · 16 · 209210.1002/adma.200400237 ↗
8. Zhang P. · Mater. Lett. · 2002 · 53 · 40010.1016/S0167-577X(01)00514-6 ↗
9. Kim T. H. · Mol. Cryst. Liq. Cryst. · 2006 · 445 · 185
10. Rossi L. M. · Langmuir · 2005 · 21 · 427710.1021/la0504098 ↗
11. Bogomolov V. N. · Phys. Rev. E · 1997 · 55 · 761910.1103/PhysRevE.55.7619 ↗
12. van Blaaderen A. · J. Colloid Interface Sci. · 1993 · 156 · 110.1006/jcis.1993.1073 ↗
13. SEM experiments were performed on a field emission scanning emission electron microscope (Raith 150 with a Leo Gemini column). SEM images were typically acquired at 10 kV without gold sputtering. Average particle size and standard deviation was determined by imaging 20 random spheres. Confidence intervals were calculated at a 95% confidence level using atvalue of 2.093.
14. García-Santamaría F. · Langmuir · 2002 · 18 · 194210.1021/la010813g ↗
15. Brankova T. · Chem. Mater. · 2003 · 15 · 185510.1021/cm0212055 ↗
16. Carlos L. D. · J. Phys. Chem. B · 2004 · 108 · 1492410.1021/jp049052r ↗
17. García J. · Mater. Chem. Phys. · 1995 · 41 · 1510.1016/0254-0584(95)01498-5 ↗