journal article·2011-08-23

Fe3Se4 Nanostructures with Giant Coercivity Synthesized by Solution Chemistry

Hongwang Zhang, Gen Long, Da Li, Renat Sabirianov, Hao Zeng

Chemistry of Materials· Volume 23· Issue 16
Publisher page

Abstract

Fe 3 Se 4 nanostructures have been synthesized by a one-pot high-temperature organic-solution-phase method. The size of these nanostructures can be tuned from 50 to 500 nm, and their shapes can be varied from nanosheets and nanocacti to nanoplatelets. These nanostructures exhibit hard magnetic properties, with giant coercivity values reaching 40 kOe at 10 K and 4 kOe at room temperature. The estimated magnetocrystalline anisotropy constant is 6 × 10 6 erg cm –3, comparable to that of hexagonal close-packed cobalt. The magnetic properties can be further tuned by substituting Fe ions by other transition-metal elements such as Co.
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Research context

OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Quantum Dots Synthesis And Properties · Iron oxide chemistry and applications

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Affiliations

Department of Physics, University at Buffalo, the State University of New York, Buffalo, New York 14260, United States

Shenyang National Laboratory for Materials Science, Institute of Metal Research and International Center for Materials Physics, Chinese Academy of Sciences, Shenyang, Liaoning 110016, China

University of Nebraska—Omaha, Omaha, Nebraska 68182, United States

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