journal article·2011-06-14

Correlations between Ion Conductivity and Polymer Dynamics in Hyperbranched Poly(ethylene oxide) Electrolytes for Lithium-Ion Batteries

Sung-Il Lee, Martina Schömer, Huagen Peng, Kirt A. Page, Daniel Wilms, Holger Frey, Christopher L. Soles, Do Y. Yoon

Chemistry of Materials· Volume 23· Issue 11
Publisher page

Abstract

Poly(ethylene oxide)s with varying degrees of hyperbranching are effective at preventing the crystallization of PEO and lead to approximately a 100-fold increase in the Li-ion conductivity below 50 °C as compared with linear PEO. The Li-ion conductivities, which increase further upon permethylation of the hydroxyl termini, are found to correlate quantitatively with the fast segmental dynamics of PEO as measured by inelastic neutron scattering.
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Research context

OpenAlex topics: Conducting polymers and applications · Advanced Battery Materials and Technologies · Fuel Cells and Related Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Seoul National University, Seoul, 151-747, Korea,

Institute of Organic Chemistry, Johannes Gutenberg-University Mainz, D-55099 Mainz, Germany,

Polymers Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, United States

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