Permeable Layers with Large Windows in [(CH3CH2CH2)2NH2]5In5Sb6S19·1.45 H2O: High Ion-Exchange Capacity, Size Discrimination, and Selectivity for Cs Ions
Source abstract
Abstract
A layered indium thioantimonate was synthesized that has extra large windows in the inorganic slabs, imparting a 3D character to the compound. High ion-exchange selectivity and high capacity for Cs+ ions were found to be associated with this novel structure.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Chemical Synthesis and Characterization · Crystal Structures and Properties · Inorganic Chemistry and Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, Northwestern University, Evanston, Illinois 60208
References (36)
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29. Synthesis of (1): An amount of 0.0408 g (0.125 mmol) of In2S3, 0.051 g (0.15 mmol) of Sb2S3, and 0.016 g (0.5 mmol) of S were combined and loaded in a 3/8 inch Pyrex tube along with 0.30 mL of 1:1 dipropylamine:water in air. The tube was then evacuated to <3 × 10-3Torr and flame-sealed. The tube was kept in an oven at ∼160 °C for 5 days. The products were isolated in air by filtration and washed with deionized water, ethanol, and ether. The product consists of pale yellow platelike crystals along with some recrystallized Sb2S3(20%). Yield was ∼60%. The crystals appear to be stable in air for months. Energy-dispersive spectroscopy (EDS) results: In4.98Sb6S18.96. C, H, N analysis (%): 14.74, 3.48, 2.87 (calcd: 14.70, 3.38, 2.86).
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