On the Crucial Role of Wetting in the Preparation of Conductive Polystyrene−Carbon Nanotube Composites

Polystyrene−single-wall carbon nanotube (PS−SWNT) nanocomposites were prepared by directly mixing aqueous suspensions of exfoliated SWNTs and PS latex particles. After freeze-drying and compression molding, homogeneous polymer films were obtained with well-dispersed carbon nanotubes, as evidenced by scanning electron microscopy imaging. The nanocomposite films display a low percolation threshold and high levels of electrical conductivity. Simultaneously, a considerable increase in the glass-transition temperature of PS is achieved, provided that a sufficient amount of low-molar-mass PS is present in the matrix material. It is suggested that a certain extent of molar mass segregation occurs in the samples, with shorter PS chains preferentially adsorbed onto the nanotube surface. The latter wetting mechanism is indispensable for obtaining favorable electrical and thermal properties.