journal article·2001-11-01

Synthesis and Characterization of the First Liquid Single-Source Precursors for the Deposition of Ternary Chalcopyrite (CuInS2) Thin Film Materials

Kulbinder K. Banger, Jonathan Cowen, Aloysius F. Hepp

Chemistry of Materials· Volume 13· Issue 11
Publisher page

Abstract

Molecular engineering of ternary single-source precursors based on the [{PBu3}2Cu(SR‘)2In(SR‘)2] architecture have afforded the first liquid CIS ternary single-source precursors (when R = Et, n-Pr), which are suitable for low-temperature deposition (<350 °C). Thermogravimetric analyses (TGA) and modulated DSC confirm their liquid phase and reduced stability. X-ray diffraction studies, EDS, and SEM support the formation of the single-phase chalcopyrite CuInS2 at low temperatures.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Chalcogenide Semiconductor Thin Films · Quantum Dots Synthesis And Properties · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Ohio Aerospace Institute, Cleveland, Ohio 44142, Department of Chemistry, Cleveland State University, Cleveland, Ohio 44115, and Photovoltaic & Space Environments Branch, NASA Glenn Research Center, Cleveland, Ohio 44135

References (10)

Show source-provided references
1. Basol B. M. · Thin Solid Films · 2000 · 361 · 51410.1016/S0040-6090(99)00823-8 ↗
2. Contreras M. · Prog. Photovoltaics · 1999 · 7 · 31110.1002/(SICI)1099-159X(199907/08)7:4<311::AID-PIP274>3.0.CO;2-G ↗
3. Schulz S. · Organometallics · 1996 · 15 · 488010.1021/om960480w ↗
4. Banger K. K. · (b) Hollingsworth, J. A.; Hepp, A. F.; Buhro, W. E. Chem. Vap. Deposition · 1999 · 5 · 105
5. Banger K. K. · 2001
6. Cowen J. · 2001
7. Hirpo W. · J. Am. Chem. Soc. · 1993 · 115 · 159710.1021/ja00057a067 ↗
8. For
10. Welch J. T. · 2000