HeterotriangulenesStructure and Properties
Source abstract
Abstract
We report the solid-state structure, electrochemical properties, and photochemical properties of 1 and 2. The single-crystal X-ray structure shows that 1 assembles into densely packed columnar π-stacks. 2 is observed as a racemic mixture of atropisomers in the solid state. The oxidation potential of 2 is similar to that of triphenylamine (∼1 V). Both 1 and 2 show strong fluorescence at 422 and 458 nm, respectively.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Crystal structures of chemical compounds · Organometallic Compounds Synthesis and Characterization · Nonlinear Optical Materials Research
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Affiliations
Department of Chemistry, University of Massachusetts, 710 N. Pleasant Street, Amherst, Massachusetts 01003
References (30)
Show source-provided references
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