Synthesis and Characterization of Highly Ordered Thiophene-Bridged Periodic Mesoporous Organosilicas with Large Pores
Source abstract
Abstract
The first example of a highly ordered periodic mesoporous thiophene-bridged organosilica (PMO) with large pores is reported. The synthesis was carried out under acidic conditions using a polyalkylene oxide triblock copolymer (Pluronic P123) as supramolecular structure-directing agent. Materials with pore sizes between 5 and 6 nm and specific surface areas in the range of 400−550 m 2 /g were obtained. The analysis of the TG/MS data demonstrates a relatively high thermal stability (up to 400 °C in air) of the mesoporous organosilica before a decomposition of the organic moieties occurs.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Mesoporous Materials and Catalysis · Polyoxometalates: Synthesis and Applications · Zeolite Catalysis and Synthesis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institute of Inorganic and Analytical Chemistry, Justus Liebig University Giessen, Heinrich-Buff-Ring 58, D-35392 Giessen, Germany
References (34)
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