journal article·1998-01-19

Solution Synthesis of Germanium Nanocrystals Demonstrating Quantum Confinement

Boyd R. Taylor, Susan M. Kauzlarich, Howard W. H. Lee, Gildardo R. Delgado

Chemistry of Materials· Volume 10· Issue 1
Publisher page

Abstract

HRTEM image of a single Ge nanocrystal. The image has been rotationally filtered to improve clarity. The lattice fringes imaged are for Ge 〈111〉, with a d spacing of 3.27 Å. Reaction between the Zintl salt NaGe and GeCl4 is shown to produce Ge nanocrystals. The reaction proceeds readily in refluxing diglyme at ambient pressure. The nanocrystals produced may be surface-terminated by reaction with RLi or RMgBr and demonstrate quantum confinement.
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Research context

OpenAlex topics: Silicon Nanostructures and Photoluminescence · Quantum Dots Synthesis And Properties · Nanowire Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, University of California, One Shields Avenue, Davis, California 95616

Lawrence Livermore National Laboratory, Livermore, California 94550

Department of Applied Science, University of California, Davis, California 95616

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