A Novel 3-Dimensional Open Framework Sulfide Based upon the [In10S20]10- Supertetrahedron: DMA-InS-SB1
Source abstract
Abstract
Hydrothermal treatment of elemental indium and sulfur in the presence of the organic structure directing agent dimethylamine yields the novel open framework material DMA-InS-SB1. This material contains [In10S20]10- supertetrahedra that corner link to form an interpenetrating “double-diamond” lattice.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Crystal Structures and Properties · Solid-state spectroscopy and crystallography · Perovskite Materials and Applications
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Affiliations
Department of Chemistry and Department of Geosciences, State University of New York, Stony Brook, New York 11794
References (21)
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1. Breck D. W. · 1984
2. Barrer R. M. · 1982
3. Bedard, R. L.; Wilson, S. T.; Vail, L. D.; Bennett, J. M.; Flanigen, E. M.Zeolites: Facts, Figures, Future; Jacobs, P. A., van Santen, R. A., Eds.; Elsevier: Amsterdam, 1989; Vol. 49, pp 375−387.10.1016/S0167-2991(08)61735-8 ↗
4. Bedard R. L. · Patent · 1989 · 4 · 880
5. Bowes C. L. · Chem. Ber · 1996 · 129 · 28710.1002/cber.19961290307 ↗
6. Bowes C. L. · Chem. Mater · 1996 · 8 · 215210.1021/cm960280a ↗
7. Cahill C. L. · Chem. Mater · 1997 · 9 · 81110.1021/cm960484r ↗
8. Tan K. · J. Am. Chem. Soc · 1995 · 117 · 7040
9. Tan K. · Chem. Mater · 1996 · 8 · 453
10. Yaghi O. M. · J. Am. Chem. Soc · 1994 · 116 · 80810.1021/ja00081a067 ↗
11. Ahari H. · Adv. Mater · 1995 · 7 · 374
12. Krebs B. · Inorg. Chim. Acta · 1982 · 65
13. Krebs B · Angew. Chem., Int. Ed. Engl · 1983 · 22 · 13410.1002/anie.198301131 ↗
14. Crystal data for DMA-InS-SB1: [(CH3)2NH2]6In10S18, orthorhombic,Pbca,a= 19.0794(10),b= 19.0878(10),c= 31.673(2) Å,V= 11534.6(10) Å,3Dc = 1.987 mg/m3, μ(Mo (Kα) = 4.569 mm-1,Z= 8, λ = 0.71073 Å, colorless hexagonal plate, 0.03 × 0.03 × 0.006 mm. Data (54,613 reflections) was collected at 23 °C on a Siemens SMART Platform CCD yielding 10 162 independent reflections (Rint= 0.0812). Solution (direct methods); refinement (full matrix least-squares refinement onF2; (SHELXTL-V5.0) [SHELXTL-Plus V5.0, Siemens Industrial Automation Inc., Madison, WI] used 4748 reflections (I> 2σ(I));R1= 0.0750,wR2= 0.1869, whereR1= ∑||Fo| − |Fc| |/∑|Fo| andwR2= √ (∑[w(Fo2−Fc2)2]/∑ [wFo4]).
15. The · Acta Crystallogr · 1990 · 46
16. Slupecki O. · Acta Crystallogr · 1982 · 38 · 107910.1107/S0567740882005007 ↗
17. Meier W. M. · 1996
18. Parise J. B. · J. Solid State Chem · 1995 · 117 · 22810.1006/jssc.1995.1267 ↗
19. Parise J. B. · Chem. Mater · 1994 · 6 · 72010.1021/cm00042a002 ↗
20. Cahill C. L. · 1997
21. Powder Diffraction File-Inorganic · PA · 1988 · 19801