journal article·2002-07-01

Synthesis and Properties of Covalently Bonded Layered Silicates/Polyimide (BTDA-ODA) Nanocomposites

Chyi-Ming Leu, Zhen-Wei Wu, Kung-Hwa Wei

Chemistry of Materials· Volume 14· Issue 7
Publisher page

Abstract

Covalently bonded layered silicates/polyimide (BTDA-ODA) nanocomposites have been synthesized from γ-(aminopropyl)triethoxysilane (APTS) grafted kenyaite and poly(amic acid). The existence of covalent bonds between APTS and silicates and between APTS and the dianhydride end groups of the polymer have been confirmed by solid-state 13 C and 29 Si nuclear magnetic resonance and infrared spectroscopy, respectively. The thermal, mechanical, and moistureabsorption retardation properties of these nanocomposites were found to improve substantially over those of neat BTDA-ODA. In particular, a maximum increase of 36 °C in the degradation temperature and a maximum reduction of 54% in moisture absorption are displayed by these nanocomposites.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Polymer Nanocomposites and Properties · Silicone and Siloxane Chemistry · biodegradable polymer synthesis and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Engineering, National Chiao Tung University, Hsinchu, Taiwan 30049, R.O.C.

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