An Exceptionally Stable Metal−Organic Framework Constructed from the Zn8(SiO4) Core
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ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTAn Exceptionally Stable Metal−Organic Framework Constructed from the Zn8(SiO4) CoreS. Y. Yang, L. S. Long, Y. B. Jiang, R. B. Huang, and L. S. ZhengView Author Information State Key Laboratory for Physical Chemistry of Solid Surface, Department of Chemistry, Xiamen University, Xiamen 361005, China Cite this: Chem. Mater. 2002, 14, 8, 3229–3231Publication Date (Web):July 17, 2002Publication History Received8 April 2002Revised24 June 2002Published online17 July 2002Published inissue 1 August 2002https://pubs.acs.org/doi/10.1021/cm025572shttps://doi.org/10.1021/cm025572srapid-communicationACS PublicationsCopyright © 2002 American Chemical SocietyRequest reuse permissionsArticle Views1343Altmetric-Citations107LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (4)»Supporting Information Supporting Information SUBJECTS:Anions,Coordination polymers,Ions,Mathematical methods,Metals Get e-Alerts
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OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Magnetism in coordination complexes · Lanthanide and Transition Metal Complexes
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State Key Laboratory for Physical Chemistry of Solid Surface, Department of Chemistry, Xiamen University, Xiamen 361005, China
References (36)
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24. Terephthalic acid [p-C6H4(COOH)2; 0.33 g, 2.0 mmol], Na2SiO3·9H2O (0.06 g, 0.2 mmol), and NaOH (0.16 g, 4 mmol) were dissolved in 35 mL of water, and 1 mol/L HNO3was added drop by drop to pH ∼ 7. Then to the above solution was added Zn(NO3)2·6H2O (0.59 g, 2.0 mmol). Finally 10 mL of ethylene glycol was added. The suspension was heated to 180 °C at the rate of 2.5 °C/h, and the resulting solution was kept at 180 °C for 100 h and then cooled to room temperature at the rate of 5 °C/h. This gave colorless cuboid crystals of the compound (0.09 g, yield 28% based on Na2SiO3·9H2O). Elem anal. Calcd for C48H24O28SiZn8: C, 36.04; H, 1.51. Found: C, 36.06; H, 1.54. FT-IR (KBr pellet): 2926(w), 1635(w), 1597(s), 1506, 1439, 1399(vs), 1319(w), 1290(w), 1161(w), 1107(w), 1019, 950, 881(w), 824, 739, 617, 562 cm-1. TGA performed on a polycrystalline sample under a flow of air showed no weight loss below ca. 500 °C. Further heating of the sample from 500 to 800 °C results in the decomposition of the material with a weight loss of 55.34%.
25. Crystal dimensions 0.36 × 0.32 × 0.29 mm, monoclinic, space groupC(2)/c,a= 19.640(4) Å,b= 14.064(3) Å,c= 19.561(4) Å,β= 90.30(3)°,V= 5403.0(19) Å3,Z= 4,ρcalcd= 1.967 g cm-3, andμ(Mo Kα) = 3.603 mm-1. Of the 5465 reflections measured (1.78 ≤ θ ≤ 25.97°), 5305 symmetry independent reflections were used to solve the structure. Based on all of these data and 370 refined parameters,R1= 0.0376,wR2= 0.0897, and the goodness of fit onF2is 0.986. The maximum and minimum peaks correspond to 0.520 and −0.393 e Å-3, respectively. Crystallographic data reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-174992. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, U.K. (fax, (+44)1223-336-033; e-mail, deposit@ ccdc.cam.ac.uk).
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