journal article·1997-10-01

Synthesis of MCM-48 by a Phase Transformation Process

Karl W. Gallis, Christopher C. Landry

Chemistry of Materials· Volume 9· Issue 10
Publisher page

Abstract

The ordered mesoporous silicate MCM-48 has been produced from MCM-41 by a phase transformation method, which involves heating the silicate samples while they are still incompletely polymerized. Ethanol, produced by hydrolysis of the silicate source TEOS, plays a crucial role in the transformation process. In this report, we examine samples produced using various combinations of stirring and heating times with XRD and 29Si MAS NMR and draw conclusions regarding the reasons for the transformation.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Mesoporous Materials and Catalysis · Zeolite Catalysis and Synthesis · Catalysis and Oxidation Reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

University of Vermont, Department of Chemistry Cook Physical Science Building Burlington, Vermont 05405

References (23)

Show source-provided references
1. Kresge C. T. · Nature · 1992 · 359 · 71010.1038/359710a0 ↗
2. Beck J. S. · J. Am. Chem. Soc. · 1992 · 114 · 1083410.1021/ja00053a020 ↗
3. Huo Q. · Chem. Mater. · 1996 · 8 · 114710.1021/cm960137h ↗
4. Huo Q. · Chem. Mater. · 1994 · 6 · 117610.1021/cm00044a016 ↗
5. Huo Q. · Nature · 1994 · 368 · 31710.1038/368317a0 ↗
6. Huo Q. · Science · 1995 · 268 · 132410.1126/science.268.5215.1324 ↗
7. Stucky G. D. · Mol. Cryst. Liq. Cryst. · 1994 · 240 · 18710.1080/10587259408029730 ↗
8. Chen C.-Y. · Microporous Mater. · 1995 · 4 · 110.1016/0927-6513(94)00077-9 ↗
9. Chen C.-Y. · Microporous Mater. · 1993 · 2 · 2710.1016/0927-6513(93)80059-4 ↗
10. Cheng C.-F. · Langmuir · 1995 · 11 · 281510.1021/la00007a075 ↗
11. Inagaki S. · J. Chem. Soc., Chem. Commun. · 1993 · 68010.1039/c39930000680 ↗
12. Inagaki S. · Bull. Chem. Soc. Jpn. · 1996 · 69 · 144910.1246/bcsj.69.1449 ↗
13. Firouzi A. · Science · 1995 · 267 · 113810.1126/science.7855591 ↗
14. Firouzi A. · J. Am. Chem. Soc. · 1997 · 119 · 359610.1021/ja963007i ↗
15. Beck J. S. · Chem. Mater. · 1994 · 6 · 181610.1021/cm00046a040 ↗
16. Israelachvili J. N. · J. Chem. Soc., Faraday Trans. 2 · 1976 · 72 · 152510.1039/f29767201525 ↗
17. Israelachvili J. N. · Biochim. Biophys. Acta · 1977 · 470 · 18510.1016/0005-2736(77)90099-2 ↗
18. Monnier A. · Science · 1993 · 261 · 129910.1126/science.261.5126.1299 ↗
19. Huo Q. · Chem. Mater. · 1997 · 9 · 1410.1021/cm960464p ↗
20. This · J. Solut. Chem. · 1986 · 15 · 14110.1007/BF00646285 ↗
21. Edler K. J. · Chem. Mater. · 1997 · 9 · 122610.1021/cm9606033 ↗
22. Si MHz
23. Engelhardt G. · 1987