Metal−Organic Scandium Framework: Useful Material for Hydrogen Storage and Catalysis
Source abstract
Abstract
The 3D polymeric terephthalate of scandium has been synthesized and its structure solved by single-crystal XRD. It was obtained as a single phase and characterized and tested as a hydrogen and nitrogen adsorbent and heterogeneous catalyst as a redox agent in the oxidation of sulfides. The compound shows a BET area of 721 m 2 g - 1 with a high C BET = 7000. The high chemical and thermal stability and excellent hydrogen sorption properties make this compound a useful material for hydrogen storage.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Advanced Photocatalysis Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, E-28049 Madrid, Spain
References (37)
Show source-provided references
1. Rossi N. L. · Science · 2003 · 300 · 112710.1126/science.1083440 ↗
2. Perles J. · Chem. Commun. · 2003 · 3 · 34610.1039/b210034g ↗
3. Perles J. · J. Mater. Chem. · 2004 · 14 · 268310.1039/b314220e ↗
4. Snejko N. · Chem. Commun. · 2002 · 13 · 1367
5. Prilezhaeva E. · Russ. Chem. Rev. · 2002 · 4 · 715
6. Kagan B. · Chem. Rev. · 2002 · 102 · 180510.1021/cr020014i ↗
7. (a) Robson, R.Comprehensive Supramolecular Chemistry; Pergamon: New York, 1996; Vol. 6, p 733.
8. Eddaoudi M. · Nature · 1999 · 402 · 27610.1038/46248 ↗
9. Moulton B. · Chem. Rev. · 2001 · 101 · 162910.1021/cr9900432 ↗
10. Braga D. · Chem. Rev. · 1998 · 98 · 137510.1021/cr960091b ↗
11. Hoskins B. F. · J. Am. Chem. Soc. · 1990 · 112 · 154610.1021/ja00160a038 ↗
12. Hagrman D. · Angew. Chem., Int. Ed. · 1997 · 36 · 87310.1002/anie.199708731 ↗
13. Miller J. S. · Adv. Mater. · 2001 · 13 · 52510.1002/1521-4095(200104)13:7<525::AID-ADMA525>3.0.CO;2-C ↗
14. Choudhury A. · J. Solid State Chem. · 2000 · 155 · 6210.1006/jssc.2000.8892 ↗
15. Thirumurugan A. · Eur. J. Inorg. Chem. · 2004 · 76210.1002/ejic.200300594 ↗
16. Pan L. · Inorg. Chem. · 2001 · 40 · 82810.1021/ic0007254 ↗
17. Reineke T. M. · J. Am. Chem. Soc. · 1999 · 121 · 165110.1021/ja983577d ↗
18. Li H. · J. Am Chem Soc. · 1998 · 120 · 857110.1021/ja981669x ↗
19. Millange F. · Chem. Commun. · 2002 · 82210.1039/b201381a ↗
20. Barthelet K. · Angew. Chem., Int. Ed. · 2002 · 41
21. Chen W. · Inorg. Chem. · 2003 · 42 · 94410.1021/ic025871j ↗
22. Barthelet K. · Chem. Commun. · 2004 · 52010.1039/B312589K ↗
23. Serre C. · J. Am. Chem Soc. · 2002 · 124 · 1351910.1021/ja0276974 ↗
24. Férey G. · Chem. Comm. · 2003 · 2355
25. International Tables for Crystallography; Kynoch Press: Birmingham, U.K., 1974; Vol. 4, p 72.
26. Siemens SAINT · 1995
27. Siemens SHELXTLTL · 1995
28. Dowty E. · 1995
29. Lippens B. C. · J. Catal. · 1965 · 4 · 31910.1016/0021-9517(65)90307-6 ↗
30. Rouquerol F. · 1999
31. Horvath G. · J. Chem. Eng. Jpn. · 1983 · 16 · 47010.1252/jcej.16.470 ↗
32. Miranda E. · J. High. Resolut. Chromatogr. · 1998 · 21 · 22510.1002/(SICI)1521-4168(19980401)21:4<225::AID-JHRC225>3.0.CO;2-Z ↗
33. Cotton S. A. · Polyhedron · 1999 · 18 · 169110.1016/S0277-5387(99)00039-X ↗
34. Zhao X. · J. Science · 2004 · 306 · 1012
35. Panel · Adv. Mater. · 2005 · 17 · 53810.1002/adma.200400946 ↗
36. Breck D. W. · 1974
37. Miller S. R. · Chem. Commun. · 2005 · 385010.1039/b506677h ↗