Synthesis and Properties of the Negative Thermal Expansion Material Cubic ZrMo2O8
Source abstract
Abstract
A new phase, cubic ZrMo2O8, has been prepared by the low-temperature dehydration of ZrMo2O7(OH)2·2H2O. This material displays isotropic negative linear thermal expansion (α = −5.0 × 10-6 K-1) over a large temperature range. Unlike the previously reported cubic ZrW2O8, it does not undergo any phase transformations on heating at atmospheric pressure, and it does not display any pressure-induced phase transformations below 0.6 GPa at room temperature.
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Research context
OpenAlex topics: Thermal Expansion and Ionic Conductivity · Magnesium Oxide Properties and Applications · Advanced Battery Materials and Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400, and Materials Science Division and Intense Pulsed Neutron Source Division, Argonne National Laboratory, Argonne, IL 60439
References (22)
Show source-provided references
1. Roy R. · Annu. Rev. Mater. Sci. · 1989 · 19 · 81
2. Sleight A. W. · Endeavour · 1995 · 19 · 6810.1016/0160-9327(95)93586-4 ↗
3. Sleight A. W. · Inorg. Chem. · 1998 · 37 · 286010.1021/ic980253h ↗
4. Mary T. A. · Science · 1996 · 272 · 9210.1126/science.272.5258.92 ↗
5. Evans J. S. O. · Chem. Mater. · 1996 · 8 · 2823
6. Evans J. S. O. · Science · 1997 · 275 · 6510.1126/science.275.5296.65 ↗
7. Perottoni C. A. · Science · 1998 · 280 · 88910.1126/science.280.5365.886 ↗
8. Prinetto F. · J. Phys. Chem. · 1995 · 99 · 556710.1021/j100015a045 ↗
9. Clearfield A. · J. Inorg. Nucl. Chem. · 1972 · 34 · 2663
10. Blasse G. · J. Phys. Chem. Solids · 1987 · 48 · 59210.1016/0022-3697(87)90058-8 ↗
11. Pankajavalli R. · J. Nucl. Mater. · 1990 · 172 · 15410.1016/0022-3115(90)90432-M ↗
12. Adachi T. · J. Nucl. Mater. · 1988 · 160 · 8710.1016/0022-3115(88)90011-6 ↗
13. Auray M. · Acta Crystallogr. · 1986 · 42 · 259
14. Auray M. · Powder Diffr. · 1987 · 2 · 3810.1017/S0885715600012215 ↗
15. Serezhkin V. N. · Russ. J. Inorg. Chem. · 1987 · 32 · 1570
16. Auray M. · Powder Diffr. · 1989 · 4 · 3010.1017/S0885715600016286 ↗
17. Palitsyna S. S. · Bull. Acad. Sci. USSR, Div. Chem. Sci. · 1977 · 611 · 613
18. Dadachov M. S. · J. Mater. Chem. · 1997 · 7 · 187010.1039/a701565h ↗
19. Jorgensen J. D. · J. App. Crystallogr. · 1989 · 22 · 33310.1107/S002188988900289X ↗
20. Larson A. C. · 1987
21. Zhdanov G. S. · Sov. Phys., Crystallogr. · 1957 · 2 · 285
22. Jorgensen J. D. · Physcia C · 1990 · 171 · 10210.1016/0921-4534(90)90460-V ↗