Recent Advances of High-Entropy Intermetallics for Electrocatalysis
Source abstract
Abstract
High-entropy intermetallics (HEIs) combining the advantages of ordered intermetallics and high-entropy alloys have been considered as highly promising candidates for electrocatalysis. Nevertheless, the comprehension and rational design of HEI electrocatalysts still lack a systematic summary. In this Review, we summarize the recent advances in HEI electrocatalysts and their applications in energy conversion reactions for the advancement of efficient electrocatalysts. At first, we propose the underlying thermodynamic mechanism and design principles of HEI electrocatalysts. After that, various synthetic strategies for HEI electrocatalysts are introduced. Furthermore, we highlight representative catalytic examples in important electrocatalytic reactions, such as the liquid fuel oxidation reaction (FOR), the oxygen reduction reaction (ORR), the hydrogen evolution reaction (HER), and so on. Finally, current issues and future perspectives on HEI electrocatalysts are presented.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Intermetallics and Advanced Alloy Properties · Electrocatalysts for Energy Conversion · Advanced Materials Characterization Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, People’s Republic of China
Funding
Ministry of Education of the People's Republic of China · National Natural Science Foundation of China · Innovation Talent Recruitment Base of New Energy Chemistry Device
References (100+)
Show source-provided references
1. 10.1126/science.aad499810.1126/science.aad4998 ↗
2. 10.1038/nature1111510.1038/nature11115 ↗
3. 10.61558/2993-074X.344410.61558/2993-074X.3444 ↗
4. 10.1038/nature1322610.1038/nature13226 ↗
5. 10.61558/2993-074X.345910.61558/2993-074X.3459 ↗
6. 10.1002/aenm.20230243610.1002/aenm.202302436 ↗
7. 10.1016/j.chempr.2023.10.00910.1016/j.chempr.2023.10.009 ↗
8. 10.1002/adma.20221188410.1002/adma.202211884 ↗
9. 10.1002/anie.20230278910.1002/anie.202302789 ↗
10. 10.1002/adem.20030056710.1002/adem.200300567 ↗
11. 10.1016/j.msea.2003.10.25710.1016/j.msea.2003.10.257 ↗
12. 10.1038/s41586-019-1617-110.1038/s41586-019-1617-1 ↗
13. 10.1063/1.496665910.1063/1.4966659 ↗
14. 10.3390/e2009065410.3390/e20090654 ↗
15. 10.1016/j.matdes.2016.01.14910.1016/j.matdes.2016.01.149 ↗
16. 10.1016/j.scriptamat.2015.10.02510.1016/j.scriptamat.2015.10.025 ↗
17. 10.1002/adem.20030050710.1002/adem.200300507 ↗
18. 10.1038/s41467-021-25264-510.1038/s41467-021-25264-5 ↗
19. 10.1016/j.msea.2008.05.02010.1016/j.msea.2008.05.020 ↗
20. 10.1002/adma.20160599710.1002/adma.201605997 ↗
21. 10.1002/crat.20210015910.1002/crat.202100159 ↗
22. 10.1002/adem.20031007410.1002/adem.200310074 ↗
23. 10.3390/e1807025210.3390/e18070252 ↗
24. 10.3390/met1112205410.3390/met11122054 ↗
25. 10.1007/s12598-021-01926-710.1007/s12598-021-01926-7 ↗
26. 10.1002/adma.20200038510.1002/adma.202000385 ↗
27. 10.1021/acs.chemrev.2c0035610.1021/acs.chemrev.2c00356 ↗
28. 10.1126/science.abn310310.1126/science.abn3103 ↗
29. 10.1126/sciadv.abm432210.1126/sciadv.abm4322 ↗
30. 10.1021/acsnano.6b0266910.1021/acsnano.6b02669 ↗
31. 10.1002/adma.20230206710.1002/adma.202302067 ↗
32. 10.1002/anie.20220088910.1002/anie.202200889 ↗
33. 10.1002/tcr.20190009010.1002/tcr.201900090 ↗
34. 10.1038/s41467-022-32842-810.1038/s41467-022-32842-8 ↗
35. 10.1021/jacs.2c0120010.1021/jacs.2c01200 ↗
36. 10.1021/jacs.0c1073910.1021/jacs.0c10739 ↗
37. 10.1002/anie.20221797610.1002/anie.202217976 ↗
38. 10.1021/acs.nanolett.3c0183110.1021/acs.nanolett.3c01831 ↗
39. 10.1038/s41467-020-19277-910.1038/s41467-020-19277-9 ↗
40. 10.1038/ncomms696410.1038/ncomms6964 ↗
41. 10.1016/j.cej.2021.13325110.1016/j.cej.2021.133251 ↗
42. 10.1002/smm2.111710.1002/smm2.1117 ↗
43. 10.1073/pnas.181564311610.1073/pnas.1815643116 ↗
44. 10.1063/1.139776210.1063/1.1397762 ↗
45. 10.1021/jacs.1c1374010.1021/jacs.1c13740 ↗
46. 10.1016/j.scib.2022.08.02210.1016/j.scib.2022.08.022 ↗
47. 10.1002/adma.20211012810.1002/adma.202110128 ↗
48. 10.1126/science.abj998010.1126/science.abj9980 ↗
49. 10.1021/jacs.3c0086810.1021/jacs.3c00868 ↗
50. 10.1039/D3EE01929B10.1039/D3EE01929B ↗
51. 10.1016/j.matt.2021.05.00510.1016/j.matt.2021.05.005 ↗
52. 10.1002/adma.20220627610.1002/adma.202206276 ↗
53. 10.1002/admi.20190001510.1002/admi.201900015 ↗
54. 10.1016/j.jallcom.2023.17047910.1016/j.jallcom.2023.170479 ↗
55. 10.1126/science.aan541210.1126/science.aan5412 ↗
56. 10.1126/science.aat147110.1126/science.aat1471 ↗
57. 10.1016/j.joule.2019.03.01410.1016/j.joule.2019.03.014 ↗
58. 10.1021/ja048121c10.1021/ja048121c ↗
59. 10.1002/adfm.20190593310.1002/adfm.201905933 ↗
60. 10.1038/s41467-022-35457-110.1038/s41467-022-35457-1 ↗
61. 10.1002/aenm.20220313610.1002/aenm.202203136 ↗
62. 10.1038/s41467-021-23426-z10.1038/s41467-021-23426-z ↗
63. 10.1021/acsnano.2c0381810.1021/acsnano.2c03818 ↗
64. 10.1016/j.jechem.2023.07.01910.1016/j.jechem.2023.07.019 ↗
65. 10.1021/acs.nanolett.3c0288210.1021/acs.nanolett.3c02882 ↗
66. 10.1002/aenm.20247003410.1002/aenm.202470034 ↗
67. 10.1002/adfm.20170225810.1002/adfm.201702258 ↗
68. 10.1002/adfm.20180785710.1002/adfm.201807857 ↗
69. 10.1039/D2CC01796B10.1039/D2CC01796B ↗
70. 10.1038/s41578-019-0121-410.1038/s41578-019-0121-4 ↗
71. 10.1021/acsami.0c0988310.1021/acsami.0c09883 ↗
72. 10.1149/09809.0343ecst10.1149/09809.0343ecst ↗
73. 10.1016/j.apcatb.2020.11860610.1016/j.apcatb.2020.118606 ↗
74. 10.1021/jacs.9b0347410.1021/jacs.9b03474 ↗
75. 10.1021/acsami.5b0196310.1021/acsami.5b01963 ↗
76. 10.1002/anie.20170233210.1002/anie.201702332 ↗
77. 10.1002/adma.20170076910.1002/adma.201700769 ↗
78. 10.1021/acscatal.2c0154110.1021/acscatal.2c01541 ↗
79. 10.1016/j.apcatb.2020.11937010.1016/j.apcatb.2020.119370 ↗
80. 10.1002/anie.20190613710.1002/anie.201906137 ↗
81. 10.1021/acscatal.9b0137510.1021/acscatal.9b01375 ↗
82. 10.1002/anie.20160008110.1002/anie.201600081 ↗
83. 10.1002/anie.20240326010.1002/anie.202403260 ↗
84. 10.1002/adfm.20220388310.1002/adfm.202203883 ↗
85. 10.1021/cr500519c10.1021/cr500519c ↗
86. 10.1039/D1CS00981H10.1039/D1CS00981H ↗
87. 10.1016/j.electacta.2015.04.09810.1016/j.electacta.2015.04.098 ↗
88. 10.1021/acs.chemrev.0c0043610.1021/acs.chemrev.0c00436 ↗
89. 10.1016/j.coelec.2017.09.02410.1016/j.coelec.2017.09.024 ↗
90. 10.1002/adfm.20231068310.1002/adfm.202310683 ↗
91. 10.1002/ange.20231089410.1002/ange.202310894 ↗
92. 10.1021/acsnano.1c0511310.1021/acsnano.1c05113 ↗
93. 10.1002/aenm.20230140810.1002/aenm.202301408 ↗
94. 10.1002/adfm.20220411010.1002/adfm.202204110 ↗
95. 10.1007/s12274-022-4432-110.1007/s12274-022-4432-1 ↗
96. 10.1016/j.isci.2022.10589010.1016/j.isci.2022.105890 ↗
97. 10.1126/sciadv.abf398910.1126/sciadv.abf3989 ↗
98. 10.1002/advs.20210476810.1002/advs.202104768 ↗
99. 10.1016/0039-6028(96)80007-010.1016/0039-6028(96)80007-0 ↗
100. 10.1016/j.cclet.2021.07.03810.1016/j.cclet.2021.07.038 ↗